A golden opportunity: molecular oxygen is found to be converted into a superoxo (O2−) species upon complexation to gold-cluster anions containing an even number of Au atoms. Vibrational spectra (see scheme) reveal small variations in the extent of O
![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
O bond activation dependent upon the electron affinity of the parent cluster.
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