Thursday, May 3, 2012

A Light-Induced Phase Exhibiting Slow Magnetic Relaxation in a Cyanide-Bridged [Fe4Co2] Complex

A Light-Induced Phase Exhibiting Slow Magnetic Relaxation in a Cyanide-Bridged [Fe4Co2] Complex: Thumbnail image of graphical abstract

Single-molecule magnets: A cyanide-bridged hexanuclear complex showed a thermal electron-transfer-coupled spin transition centered at 220 K. Light irradiation at low temperature (LT; HT=high temperature) generated a metastable state showing slow magnetic relaxation in measurements of the alternating-current magnetic susceptibility (χm; see picture).


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